Chloridomethyl(2-methylquinolin-8-olato-κ2 N,O)phenyltin(IV)
نویسندگان
چکیده
The asymmetric unit of the title complex, [Sn(CH(3))(C(6)H(5))(C(10)H(8)NO)Cl], consists of two independent mol-ecules, both of which have the N,O-chelated Sn(IV) atom in a cis-C(2)SnNOCl trigonal-bipyramidal geometry [C-Sn-C = 124.82 (8) and 137.69 (8)°]. The Cl atom of the mol-ecule with the smaller C-Sn-C angle inter-acts weakly with the Sn(IV) atom of the mol-ecule with the wider C-Sn-C angle at an Sn⋯Cl distance of 3.595 (1) Å. Weak inter-molecular C-H⋯O and C-H⋯Cl hydrogen bonding is present in the crystal structure.
منابع مشابه
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In the disolvated title salt, (C(13)H(10)NO)[SnCl(4)(C(10)H(8)NO)]·2CH(3)OH, the Sn(IV) atom is chelated by the N,O-bidentate 2-methyl-quinolin-8-olate ion and is further coordinated by four chloride ions, showing a distorted octa-hedral SnNOCl(4) geometry. In the crystal, the cation and anion are linked to the methanol mol-ecules by O-H⋯O and N-H⋯O hydrogen bonds.
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010